EP 4 190 758 A1

Method for
regulating alite
crystal structure in cement clinker

(22) 11.08.2021

(43) 07.06.2023

(57) Disclosed is a method for regulating an alite crystal structure in a cement clinker. In a preparation process of a Portland cement raw meal, a magnesium element and a sulfur element are simultaneously introduced, and M3-type alite in the clinker is completely converted into M1-type alite under the joint action of the magnesium element and the sulfur element. Raw materials used in the method for regulating the crystal structure in the invention are easily available, and the method is simple and easy to operate, and has high universality. Des-sulfurized gypsum, phospho gypsum and the like can be used as sources of sulfur in actual production, so that a comprehensive utilization value of an industrial by-product is increased. Magnesium can be derived from low-quality limestone, and no additional ingredient components need to be added, so that not only convenient operation is realized, but also the use of the low-quality limestone is increased, thus reducing production costs. After being regulated by the method, the alite crystal structure in the Portland cement clinker can be completely converted from M3-type or M1/M3 hybrid type into M1-type.

(71) Nanjing Tech University Nanjing Jiangsu 210000 (CN); Jiangsu Ruiying Advanced Materials Technology Development Co., Ltd Suqian, Jiangsu 210000 (CN)

(84) Designated Contracting States: AL AT BE BG CH CY CZ DE DK EE ES Fl FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR; Designated Extension States: BA ME; Designated Validation States: KH MA MD TN

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