Hydrophobizing of gypsum by silanes (Part 1)

1 Relative reaction rate vrel for hydrolysis and condensation reaction of silanes as a function of pH [15, 20]
2 Water uptake reduction expressed by water drop absorption time (water drop test) of gypsum surface as a function of the content of the alkyltriethoxysilanes PTES and OTES
3 Hydrophobicity (water drop test) of gypsum surface with varying content of a- and b-hemihydrates with 0.165 wt% PTES based on the dry mix
4 Hydrophobicity (water drop test) of gypsum surface as a function of the hydrolysis time of 0.165 wt% propyltriethoxysilane (PTES). Hydrolysis time = pre-hydrolysis time of silane in alkaline suspension + 15 min. workability time of fresh mortar
5 Comparison of the 13C-NMR-spectra of propyltriethoxysilane (0,5 wt%) at pH 12.5 after various times of hydrolysis
6 Comparison of the 29Si-NMR-spectra of propyltriethoxysilane and reaction species at pH 3 (left) and 12.5 (right) after 35 min time of hydrolysis
Water drop test on a gypsum surface

The main disadvantage of gypsum products in the building industry is the poor water resistance. While it is known that the water resistance can be increased by adding special silanes, only very little is known about the working mechanism of such silanes. The mechanism of the hydrophobizing effect of propyltriethoxysilane as a representative for a short chain alkylalkoxysilane in an alkaline gypsum matrix is studied in detail.

1 Introduction

Gypsum products are used in a wide range of applications, primarily in the building material sector. The most important are gypsum and gypsum-lime plasters, plaster boards, gypsum fiber boards, standard wall boards or plaster floors. Despite a low solubility of 2.75 g gypsum/L water gypsum products have a high water sensitivity. This limits the use to indoor applications. Gypsum can absorb water reversibly via the pore system, whereas swelling caused by water mass transport can result in significant reduction of strength and surface damage. The increase of the water resistance of...

TEXT Dipl. Chem. Andrea Winkler1, Dipl. Nat. Susanne Fritz1, Dr. Thomas Aberle2, Dr. Daniela Freyer1*, Prof. Dr. Wolfgang Voigt1
1TU Bergakademie Freiberg, Institute of Anorganic Chemistry, Freiberg/Germany
2Akzo Nobel Chemicals AG, Sempach-Station/Switzerland

This article appeared in

ZKG 7-8/2013

This article appeared in

ZKG 7-8/2013

Ressort:  Process
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